<span><strong>Spectral characterization of tetradentate Schiff base complexes of N<sub>2</sub>O<sub>2</sub> donor groups</strong></span>
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Title Statement |
<span><strong>Spectral characterization of tetradentate Schiff base complexes of N<sub>2</sub>O<sub>2</sub> donor groups</strong></span> |
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Added Entry - Uncontrolled Name |
Kumar, Deo Nandan; Deshbandhu College
(University of Delhi)
Kalkaji, New Delhi-110019
Phone No.: 011 28091036; +91 9868425279 |
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Uncontrolled Index Term |
Synthetic and structural inorganic chemistry Spectral data, Schiff base, Copper (II), thermal studies |
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Summary, etc. |
<p><span>Copper(II) complexes of tetra dentate Schiff bases N, N’ – disalicylidene – 1, 2 – phenylenediamine(H<sub>2</sub>dsp), N, N’ – disalicylidene – 3, 4 – diaminotoluene(H<sub>2</sub>dst),<span> </span>4 – nitro - N, N’ – disalicylidene – 1, 2 – phenylenediamine(H<sub>2</sub>ndsp), N, N’ – disalicylideneethylenediamine(H<sub>2</sub>salen) have been synthesized and characterized by elemental analysis, electronic spectra, IR spectra, magnetic susceptibility measurement, EPR, CV and thermal studies. TG studies show that Cu(dsp) and Cu(ndsp) complexes thermally degrade in two steps and Cu(dst) and Cu(salen) in one step. Kinetic and thermodynamic parameters were computed from thermal decomposition data. The activation energies of both the thermal degradation step lie in between 52 – 74 kJ/mol .</span></p> |
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Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2020-10-05 12:32:52 |
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Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/25787 |
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Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 59, ##issue.no## 2 (2020): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
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Language Note |
en |
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Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCA/article/download/25787/465480256 http://op.niscair.res.in/index.php/IJCA/article/download/25787/465480257 http://op.niscair.res.in/index.php/IJCA/article/download/25787/465480259 |
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