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<p>Cordierite honeycomb supported Mo(VI)/ZrO2 for Microwave assisted Pinacol-Pinacolone rearrangement</p><p> </p><p> </p>

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Title Statement <p>Cordierite honeycomb supported Mo(VI)/ZrO2 for Microwave assisted Pinacol-Pinacolone rearrangement</p><p> </p><p> </p>
 
Added Entry - Uncontrolled Name sarithaserrao, reena ; HMSIT
Shamshuddin, Mohamed sz; HMSIT, Tumakuru
D'Souza, Joyce ; ST. Joseph's College
Yaseen, Mubarak
VGST, Govt of Karnataka
 
Uncontrolled Index Term catalysis, organic synthesis
Pinacol rearrangement, Zirconia, solid acids, Microwave
 
Summary, etc. ZrO2, Mo(VI)/ZrO2 and Pt-SO42-/ZrO2 supported on honeycomb monoliths were prepared and characterized for their physico-chemical propertiess such as surface acidity, crystallinity, functionality and morphology.  These materials were used as solid acid catalysts in the pinacol rearrangement of benzopinaol via microwave irradiation.  Few diols were also subjected to pinacol rearrangment to obtain high yield of rearrangement products with good selectivity.  Optimization of reaction conditions was also studied to determine most suitalbe for the effective synthesis pinacolone derivatives.  Up to 98% conversion of benzopinacol was achieved under a set of optimised reaction conditions.  A reactivation and reusbility study of zirconia basd solid acids was also taken up.
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-05 12:32:52
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCA/article/view/23885
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 59, ##issue.no## 2 (2020): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/23885/465474699
http://op.niscair.res.in/index.php/IJCA/article/download/23885/465474700
http://op.niscair.res.in/index.php/IJCA/article/download/23885/465474702
http://op.niscair.res.in/index.php/IJCA/article/download/23885/465474703
http://op.niscair.res.in/index.php/IJCA/article/download/23885/465474704
 
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