<strong><span>Calculation of thermodynamic properties of the most important forty-seven different solvents for create a information data bank by semi-empirical quantum methods used determination of theoretical pKa</span></strong>
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Title Statement |
<strong><span>Calculation of thermodynamic properties of the most important forty-seven different solvents for create a information data bank by semi-empirical quantum methods used determination of theoretical pKa</span></strong> |
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Added Entry - Uncontrolled Name |
İslamoğlu, Fatih ; Recep Tayyip Erdoğan University Erdoğan, Naciye ; Recep Tayyip Erdoğan University |
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Uncontrolled Index Term |
Theoretical & quantum chemistry theoretical & quantum chemistry; analytical chemistry |
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Summary, etc. |
<p>In this study, we calculated the thermodynamic properties, especially in determining the theoretical acidic properties and pKa values of organic compounds, as enthalpy (∆H, kcal/mol), heat capacity (C, cal/Kmol), entropy (∆S, cal/Kmol) and free energy (∆G, kcal/mol) of 47 different solvents with the MOPAC 2016 computer program at 298 K used in semi-empirical quantum methods (PM7, PM6, PM6-DH2, RM1, PM3, AM1 and MNDO). Evaluations were made between these values and the used methods. At the same time, a data bank was created with these obtained values for the researchers who will do scientific study for the theoretical pKa.</p> |
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Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2020-10-06 11:19:13 |
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Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/30076 |
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Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 59, ##issue.no## 7 (2020): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
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Language Note |
en |
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Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCA/article/download/30076/465492473 http://op.niscair.res.in/index.php/IJCA/article/download/30076/465492474 http://op.niscair.res.in/index.php/IJCA/article/download/30076/465492475 http://op.niscair.res.in/index.php/IJCA/article/download/30076/465492969 http://op.niscair.res.in/index.php/IJCA/article/download/30076/465492970 http://op.niscair.res.in/index.php/IJCA/article/download/30076/465492971 http://op.niscair.res.in/index.php/IJCA/article/download/30076/465492973 http://op.niscair.res.in/index.php/IJCA/article/download/30076/465492974 http://op.niscair.res.in/index.php/IJCA/article/download/30076/465492975 |
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