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Enantioselective bioreduction of heptan-2-one and octan-2-one catalyzed by Daucus carota cells
NOPR - NISCAIR Online Periodicals Repository
View Archive Info| Field | Value | |
| Title |
Enantioselective bioreduction of heptan-2-one and octan-2-one catalyzed by Daucus carota cells
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| Creator |
Chanysheva, Aliya R
Zorin, Vladimir V |
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| Subject |
Daucus carota
Bioreduction Exogenous reducing agents (2S)-(+)-heptan-2-ol (2S)-(+)-octan-2-ol |
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| Description |
1381-1383
Synthesis of enantiomerically pure (2S)-(+)-heptan-2-ol and (2S)-(+)-octan-2-ol by bioreduction of heptan-2-one and octan-2-one using Daucus carota cells has been studied. Optimization of bioreduction conditions has been carried out in the presence of various exogenous reducing agents (ethanol, isopropanol, glucose). Conditions allowing to obtain (2S)-(+)-heptan-2-ol with 91% yield and optical purity 98% ee and (2S)-(+)-octan-2-ol in 95% yield and > 99% ee have been found. |
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| Date |
2020-10-09T05:19:50Z
2020-10-09T05:19:50Z 2020-09 |
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| Type |
Article
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| Identifier |
0975-0983(Online); 0376-4699(Print)
http://nopr.niscair.res.in/handle/123456789/55448 |
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| Language |
en_US
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| Rights |
 CC Attribution-Noncommercial-No Derivative Works 2.5 India
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| Publisher |
NISCAIR-CSIR, India
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| Source |
IJC-B Vol.59B(09) [September 2020]
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