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<p class="ListParagraph1">Synthesis, Characterization and Catalytic activity of Cu(II) schiff base complexes intercalated in layered double hydroxide for the oxidation of Styrene</p>

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Title Statement <p class="ListParagraph1">Synthesis, Characterization and Catalytic activity of Cu(II) schiff base complexes intercalated in layered double hydroxide for the oxidation of Styrene</p>
 
Added Entry - Uncontrolled Name Parashar, Swati ; Devi Ahilya Vishwavidyalaya, Indore
Khare, Savita ; Devi Ahilya Vishwavidyalaya, Indore
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Uncontrolled Index Term catalysis; analytical chemistry; spectroscopy
Layered double hydroxides; heterogeneous catalyst; styrene; oxidation; tert-butyl hydroperoxide
 
Summary, etc. A heterogeneous copper schiff  base complex intercalated in layered double hydroxide, abbreviated as LDH-[SALABA-Cu(II)] has been synthesized and characterized by various analytical techniques like XRD, FTIR, SEM, ICP-AES, TGA, BET surface area, XPS etc. Its catalytic activity is examined for oxidation of styrene using 70% <em>tert</em>-butyl hydroperoxide as an oxidant in acetonitrile solvent. The oxidation products are styrene oxide, benzaldehyde and benzoic acid, in which styrene oxide is obtained as major oxidation product under optimized conditions. A maximum 81.27% conversion of styrene is obtained after 5 h of reaction. The catalyst, LDH-[SALABA-Cu(II)] is recycled ten times in consecutive runs without much loss of catalytic activity. Quenching study has also been performed using p-benzoquinone in order to find out the mode of mechanism.
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-12 16:09:18
 
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http://op.niscair.res.in/index.php/IJCA/article/view/24401
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 58, ##issue.no## 7 (2019): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/24401/465476284
http://op.niscair.res.in/index.php/IJCA/article/download/24401/465476286
http://op.niscair.res.in/index.php/IJCA/article/download/24401/465476288
 
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