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<p><strong> </strong></p> <p><strong>Synthesis and crystal structure of a new acetate bridged metal-organic framework constructed by Pr (III) with 5-aminoisophthalic acid-</strong><strong> [Pr(CH<sub>3</sub>COO)(AIP)(H<sub>2</sub>O)<sub>2</sub>]<sub>n </sub>.<sub> </sub>nH<sub>2</sub>O</strong><strong> </strong></p>

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Title Statement <p><strong> </strong></p> <p><strong>Synthesis and crystal structure of a new acetate bridged metal-organic framework constructed by Pr (III) with 5-aminoisophthalic acid-</strong><strong> [Pr(CH<sub>3</sub>COO)(AIP)(H<sub>2</sub>O)<sub>2</sub>]<sub>n </sub>.<sub> </sub>nH<sub>2</sub>O</strong><strong> </strong></p>
 
Added Entry - Uncontrolled Name A, Ashalatha ; Department of Chemistry Mahatma Gandhi College
Sudarsanakumar, MR ; Department of Chemistry Mahatma Gandhi College
Satheesh Chandran, PR ; Department of Chemistry Mahatma Gandhi College
Danya, V S ; Department of Chemistry Mahatma Gandhi College
UGC- FDP
 
Uncontrolled Index Term Synthetic and structural inorganic chemistry
Metal- organic framework; Gel diffusion technique; 5 -aminoisophthalic acid;  praseodymium complex.
 
Summary, etc. <p>A novel acetate bridged lanthanide complex [Pr(CH<sub>3</sub>COO)(AIP)(H<sub>2</sub>O)<sub>2</sub>]<sub>n </sub>.nH<sub>2</sub>O <strong>(PAIT)</strong> (H<sub>2</sub>AIP=5-aminoisophthalic acid)  has been synthesized at room temperature by gel  diffusion technique using hydro silica gel and structurally characterized by single crystal X-ray  diffraction (CIF file CCDC no. 1857252). The title compound crystallizes in monoclinic space group, P2<strong><sub>1</sub></strong>/c with a=10.5618(8) Å, b =12.1510(9) Å, c =10.7510(9) Å, α =90°, β =94.696(6) ° , γ=90°<strong>.</strong> The Pr<sup>3+</sup> ion is coordinated by O<sub>9</sub> donor sets to form distorted tricapped triagonal prism geometry. Its structure features a 3D polymeric network possessing ‘S’ shaped hydrophilic pores. <strong></strong></p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-12 16:10:18
 
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http://op.niscair.res.in/index.php/IJCA/article/view/24123
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 58, ##issue.no## 8 (2019): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/24123/465475445
http://op.niscair.res.in/index.php/IJCA/article/download/24123/465475450
http://op.niscair.res.in/index.php/IJCA/article/download/24123/465475624
 
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