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<h2><span style="font-family: "times new roman", times;"><strong>Luminescent rhenium(I) complex of azo ligand based on quinoline: Synthesis, characterization and computational investigations</strong></span></h2>
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dc |
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| Title Statement |
<h2><span style="font-family: "times new roman", times;"><strong>Luminescent rhenium(I) complex of azo ligand based on quinoline: Synthesis, characterization and computational investigations</strong></span></h2> |
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| Added Entry - Uncontrolled Name |
Sinha, Debopam ; Jadavpur University Parua, Sankar Prasad; Jadavpur University Rajak, Kajal Krishna; Jadavpur University UGC; DST-SERB |
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| Uncontrolled Index Term |
Synthetic and structural inorganic chemistry; theoretical & quantum chemistry; spectroscopy Mononuclear Re(I) complex, X-ray structure; photoluminescence; Life time; Computational studies |
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| Summary, etc. |
Reaction of 7-(quinolin-8-yldiazenyl)quinolin-6-ol HL, [where H represents the dissociable proton upon complexation] based on quinoline with [Re(CO)<sub>5</sub>Cl] in toluene afforded brown colored product of composition [(Re(CO)<sub>3</sub>L]. The mononuclear Re(I) complex was characterized unequivocally. Molecular structure of the complex <em>fac</em>-[(Re(CO)<sub>3</sub>L] was confirmed by single-crystal X-ray diffraction. The complex exhibited excellent photoluminescence behavior in solution state. The ground and excited-state geometries and absorption properties of the Re(I), complex was further examined by DFT and TDDFT methods |
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| Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2020-10-12 16:08:25 |
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| Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/23842 |
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| Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 58, ##issue.no## 6 (2019): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
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| Language Note |
en |
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| Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCA/article/download/23842/465474522 http://op.niscair.res.in/index.php/IJCA/article/download/23842/465474523 http://op.niscair.res.in/index.php/IJCA/article/download/23842/465474524 http://op.niscair.res.in/index.php/IJCA/article/download/23842/465474525 http://op.niscair.res.in/index.php/IJCA/article/download/23842/465476654 http://op.niscair.res.in/index.php/IJCA/article/download/23842/465476655 http://op.niscair.res.in/index.php/IJCA/article/download/23842/465476656 |
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