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<p>Phase Transformation of Boron Nitride Nanoparticles in Aniline under Moderate Conditions</p>

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Title Statement <p>Phase Transformation of Boron Nitride Nanoparticles in Aniline under Moderate Conditions</p>
 
Added Entry - Uncontrolled Name Zhu, Lingling
Liu, Luoqiang
Zhang, Xing
Lu, Xifeng
He, Lifei
Cui, Deliang
 
Uncontrolled Index Term sp3-bonded boron nitride; nanoparticles; phase transformation; aniline; temperature and pressure
 
Summary, etc. <p>In order to synthesize sp<sup>3</sup>-bonded phases wurtzitic boron nitride (wBN) and cubic boron nitride (cBN) at moderate conditions, phase transformations of boron nitride (BN) nanoparticles in aniline were investigated in terms of temperature, pressure and surface modification by solvothermal hot-press method. The results reveal that sp<sup>3</sup>-bonded phases wBN and cBN formed at quite low temperature (250~280 °C) and low pressure (15~250 MPa) because the incorporation of bonding interactions between aniline and BN nanoparticles would induce the formation of sp<sup>3</sup>-bonded configurations with minimum energy. A simple model was proposed to explore the phase transformation mechanism of BN nanoparticles in aniline under hot-press conditions.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-12 16:10:18
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCA/article/view/22705
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 58, ##issue.no## 8 (2019): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/22705/465471064
http://op.niscair.res.in/index.php/IJCA/article/download/22705/465471852
 
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