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<p class="Default"><strong>Ultrasonically Promoted Synthesis of N-benzylmorpholine under          Polymer-Supported Phase-Transfer Catalysis Condition – A kinetic study</strong></p>

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Title Statement <p class="Default"><strong>Ultrasonically Promoted Synthesis of N-benzylmorpholine under          Polymer-Supported Phase-Transfer Catalysis Condition – A kinetic study</strong></p>
 
Added Entry - Uncontrolled Name SATHIYARAJ, MANICKAM ; University of madras Chennai PG & Research, Department of Chemistry, Pachaiyappa’s College, Chennai, Tamil Nadu, India - 600 030
Venkatesh, Perumal ; University of madras Chennai PG & Research, Department of Chemistry, Pachaiyappa’s College, Chennai, Tamil Nadu, India - 600 030
Rajendran, Venugopal ; University of madras Chennai PG & Department of Chemistry, Pachaiyappa’s College for Men, Kanchipuram, Tamil Nadu, India - 631 501
Mohammadiliyas, Mohammadbilal ; University of madras Chennai PG & Department of Chemistry, Pachaiyappa’s College for Men, Kanchipuram, Tamil Nadu, India - 631 501
Selvaraj, Varathan ; University of madras Chennai PG & Department of Chemistry, Sri Akilandeswari Women’s College,Wandiwash, Tamil Nadu, India – 604 408
 
Uncontrolled Index Term catalysis and analytical chemistry
Phase-transfer catalysis; Polymer-supported phase-transfer catalyst; Ultrasound irradiation; Morpholine; Benzyl Chloride; Solid-liquid reaction; Kinetics.
 
Summary, etc. <p><strong>Abstract</strong></p> <p><strong> </strong>In the present study, kinetics of synthesis of N-benzylmorpholine was successfully carried out by morpholine with benzyl bromide using aqueous potassium hydroxide and catalyzed by a newly synthesized polymer supported mono-site phase - transfer catalyst viz.,    Polymer supported N-benzyl-N-ethyl-N-isopropylpropan-2-aminium bromide (PSPTC)<strong>,</strong> under ultrasonic (40 kH<sub>Z</sub>, 300W) assisted organic solvent condition. The pseudo first-order kinetic equation was applied to describe the overall reaction. Under ultrasound irradiation (40 kHz, 300W) in a batch reactor, it shows that the overall reaction rate can be greatly enhanced with ultrasound irradiation than without ultrasound. Peculiar phenomenon for the dependence of the reaction rate on the amount of PSPTC and ultra sonication are explained satisfactorily.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-12 14:00:53
 
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http://op.niscair.res.in/index.php/IJCA/article/view/22398
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 58, ##issue.no## 1 (2019): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470168
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470169
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470170
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470171
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470172
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470175
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470180
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470181
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470435
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465470816
http://op.niscair.res.in/index.php/IJCA/article/download/22398/465471391
 
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