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<p><strong>Interaction of Indenopyridines with [60]-fullerene: A spectroscopic and computational study</strong></p>

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Authentication Code dc
 
Title Statement <p><strong>Interaction of Indenopyridines with [60]-fullerene: A spectroscopic and computational study</strong></p>
 
Added Entry - Uncontrolled Name Chaudhuri, Tandrima ; Dr. Bhupendranath Dutta Smriti Mahavidyalaya, Burdwan University.
UGC, India
 
Uncontrolled Index Term Indenopyridines; Fullerene
Indenopyridines, Fullerene, Isosbestic formation, DFT, electrochemical indices
 
Summary, etc. <p><strong>Abstract</strong></p> <p>Heterocyclic polynuclear planar indenopyridines (I1, I3 and I4) revealed superior wrapping of [60]-fullereneand formed stable ground state equilibrium defined via formation of absorption isosbestic and isoemissive as well. All three indenopyridines showed almost similar order of ground state formation constant both in Benesi-Hildebrand and in Stern-Volmer method with[60]-fullerene in toluene medium. DFT based computation warranted the experimental finding in terms of loss of planarity of indenopyridines, FMO features to define electron donor and acceptor, electrochemical indices to affirm the direction of electron swing and finally TD-DFT calculation showed HOMO to (LUMO+2) was most pronounced transition for the strongest binding with I4.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-12 16:06:45
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCA/article/view/22798
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 58, ##issue.no## 5 (2019): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/22798/465471339
http://op.niscair.res.in/index.php/IJCA/article/download/22798/465471344
http://op.niscair.res.in/index.php/IJCA/article/download/22798/465471601
 
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