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<p><strong>Oxidation of Phenol and Toluene over Polymer Supported Co(II) and Fe(III) Catalysts</strong></p>

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Title Statement <p><strong>Oxidation of Phenol and Toluene over Polymer Supported Co(II) and Fe(III) Catalysts</strong></p>
 
Added Entry - Uncontrolled Name Gayathri, V ; BANGALORE UNIVERSITY
 
Uncontrolled Index Term Co(PS-BBP)Cl2; Fe(PS-BBP)Cl3; TBHP; Toluene; Phenol
 
Summary, etc. <p>Polymer supported iron and cobalt complexes of 2,6-bis(benzimidazolyl)pyridine (BBP) abbreviated as Fe(PS-BBP)Cl<sub>3</sub> and Co(PS-BBP)Cl<sub>2</sub> exhibited catalytic activity towards oxidation of phenol and toluene to give catechol and benzaldehyde as major products respectively using TBHP as oxidant. The influences of temperature, reaction time, solvents, concentration of catalyst, substrate to oxidant ratio and oxidants on the oxidation reactions were studied. At optimized conditions, Fe(PS-BBP)Cl<sub>3</sub> gave 92.3 % conversion of phenol and 88.2 % toluene whereas,  Co(PS-BBP)Cl<sub>2 </sub>gave 97.5 and 86.3 % conversion of phenol and toluene respectively. Catalysts are recyclable without loss in their activity and possible mechanisms of these reactions were also worked out.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-12 16:15:21
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCA/article/view/23704
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 58, ##issue.no## 9 (2019): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/23704/465474115
http://op.niscair.res.in/index.php/IJCA/article/download/23704/465474266
http://op.niscair.res.in/index.php/IJCA/article/download/23704/465476950
 
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