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<p><strong><span>Studies on coordination environment of transition metal chloride anionic speciation of N, N-disulfodiisopropylammonium ionic salts and assessment of their Br</span></strong><span>ö<strong>nsted-Lewis acidic properties </strong></span></p>

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Title Statement <p><strong><span>Studies on coordination environment of transition metal chloride anionic speciation of N, N-disulfodiisopropylammonium ionic salts and assessment of their Br</span></strong><span>ö<strong>nsted-Lewis acidic properties </strong></span></p>
 
Added Entry - Uncontrolled Name Borah, Ruli ; Tezpur University
Science and Engineering Research Board, India
 
Uncontrolled Index Term Inorganic-organic ionic material
Brönsted-Lewis acidic, Chlorometallates, Anionic speciation, Transition metal cation, Ammonium cation
 
Summary, etc. <p>Four ionic salts of N, N-disulfodiisopropylammonium cation with complex anionic speciation of metal chlorides such as [FeCl<sub>4</sub>]<sup>-</sup>, [NiCl<sub>4</sub>]<sup>2-</sup>, [Zn<sub>2</sub>Cl<sub>6</sub>]<sup>2-</sup>/[Zn<sub>4</sub>Cl<sub>10</sub>]<sup>2-</sup>, [CoCl<sub>4</sub>]<sup>2-</sup>/[CoCl<sub>3</sub>]<sup>- </sup>were synthesized and characterized with FT-IR, NMR, TGA, Raman and electronic spectra. Comparative Brönsted acidic and Lewis acidic strength of the salts were assessed for catalytic uses in organic reactions <em>via</em> UV-Vis Hammett plot and FT-IR spectra using pyridine as probe molecule respectively. Band gap values obtained from Tauc plot present their semiconductor behavior to design ionic liquid based photo catalysts in future.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-14 10:10:40
 
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http://op.niscair.res.in/index.php/IJCA/article/view/30736
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 59, ##issue.no## 10 (2020): INDIAN JOURNAL OF CHEMISTRY - SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/30736/465494462
http://op.niscair.res.in/index.php/IJCA/article/download/30736/465494463
 
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