<p>Metal supported and metal ion exchanged catalysts from palygorskite for acetylation reaction</p>
Online Publishing @ NISCAIR
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Title Statement |
<p>Metal supported and metal ion exchanged catalysts from palygorskite for acetylation reaction</p> |
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Added Entry - Uncontrolled Name |
AP, DhanyaBalan A P Balan; Govt.College Kasaragod
Under Kannur University KSCSTE |
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Uncontrolled Index Term |
Catalysis Catalysts, Supported catalysts, Solid catalysts, Cation exchange capacity, Acid activation, Acetylation, Palygorskite, Acetic acid, Alcohols |
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Summary, etc. |
Efficient solid acid catalysts from palygorskite have been developed by three modification methods, viz., acid activation, metal salt support (with FeCl<sub>3</sub>, MnCl<sub>2</sub>, CoCl<sub>2</sub>, SnCl<sub>2</sub>, ZnCl<sub>2 </sub>and AlCl<sub>3</sub>) and metal ion exchange (exchange with Fe<sup>3+</sup>, Mn<sup>2+,</sup> Co<sup>2+</sup>, Sn<sup>2+</sup>, Zn<sup>2+ </sup>and Al<sup>3+</sup>) for acetylation reaction in the liquid phase. The prepared catalysts are characterized by XRD, SEM, FTIR, NH<sub>3</sub>-TPD, cation exchange capacity, and BET surface area, and their catalytic activity tested by acetylation of primary and secondary alcohols using acetic acid. The modified palygorskites are found to be efficient catalysts for acetylation of alcohols with no loss of catalytic activity even after four cycles. The iron exchanged palygorskite is found to be most active. |
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Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2020-10-19 12:58:13 |
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Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/16827 |
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Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 57, ##issue.no## 5 (2018): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
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Language Note |
en |
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Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCA/article/download/16827/50931 http://op.niscair.res.in/index.php/IJCA/article/download/16827/51054 http://op.niscair.res.in/index.php/IJCA/article/download/16827/51187 |
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