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<p>Synthesis and structure characterization of two cadmium coordination polymers based on μ<sub>2</sub>-bridging bidentate hydrazine ligand</p>

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Title Statement <p>Synthesis and structure characterization of two cadmium coordination polymers based on μ<sub>2</sub>-bridging bidentate hydrazine ligand</p>
 
Added Entry - Uncontrolled Name D, SANTHOSH SHANTHAKUMAR ; Sri Krishna College of Technology, Coimbatore-641042, Tamilnadu, India.
R, PRADEEP ; Government Arts College, Udhagamandalam, The Nilgiris - 643 002, Tamilnadu, INDIA
B. N., SIVASANKAR ; Government Arts College, Udhagamandalam, The Nilgiris - 643 002, Tamilnadu, INDIA
 
Uncontrolled Index Term Coordination polymers, Cadmium coordination polymers, Crystal structures, Hydrazines, Malonates, μ2-Bridging bidentate, μ3-Bridging pentadentate
 
Summary, etc. <p>Synthesis, single crystal structures, spectral and thermal characteristics of two cadmium coordination polymers, viz., [Cd(NO<sub>3</sub>)<sub>2</sub>(N<sub>2</sub>H<sub>4</sub>)<sub>2</sub>] (<strong>1</strong>) [Cd(C<sub>3</sub>H<sub>2</sub>O<sub>4</sub>)(N<sub>2</sub>H<sub>4</sub>)] (where C<sub>3</sub>H<sub>2</sub>O<sub>4 </sub>is malonate) (<strong>2</strong>) are reported. The μ<sub>2</sub>-bridging bidentate binding mode of the crystallographically unique hydrazine ligands in <br /> (<strong>1</strong>) leads to a one-dimensional polymeric structure extending along <em>c</em> axis. The central Cd(II) in (<strong>2</strong>) exhibits hepta-coordination and is bonded to a unique malonate anion which exhibits a μ<sub>3</sub>-bridging pentadentate coordination, extending the structure along the <em>a</em> axis. The bridging bidentate binding of the crystallographically independent hydrazine ligand extends along <em>b</em> axis resulting in a 2-D structure.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-19 14:04:12
 
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http://op.niscair.res.in/index.php/IJCA/article/view/17136
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 57, ##issue.no## 7 (2018): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/17136/51332
http://op.niscair.res.in/index.php/IJCA/article/download/17136/51333
http://op.niscair.res.in/index.php/IJCA/article/download/17136/51557
http://op.niscair.res.in/index.php/IJCA/article/download/17136/51558
 
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