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Functional 1,8-naphthyridine copper(I) complex as efficient catalyst for <em>n</em>-arylation of imidazoles coupling reactions<br />

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Title Statement Functional 1,8-naphthyridine copper(I) complex as efficient catalyst for <em>n</em>-arylation of imidazoles coupling reactions<br />
 
Added Entry - Uncontrolled Name Gou, Gaozhang ; Honghe University
the National Natural Science Foundation of China, PR China (61361002, 21262049 and 21362010), the “Chun Hui” Plan of Chinese Ministry Education, PR China (Z2011125), the Scientific Research Foundation of Education Department of Yunnan Province, PR China (
 
Uncontrolled Index Term Synthetic and structural inorganic chemistry; catalysis chemistry
Catalysts, Cross-coupling reactions, N-Arylation, Copper(I) complex, Imidazoles
 
Summary, etc. The functional 1,8-naphthyridine copper(I) complex, synthesized through a non-catalyst C(<em>sp</em><sup>3</sup>)–H methylenation, catalyzes the cross-coupling reaction of aryl halides with imidazoles, by C―N bond formation. The Cu(I) complex catalyzes the reaction with a low catalyst loading (1%, molar fraction) and cheap base even under aerobic conditions. The procedure tolerates aryl halides with various functional groups (such as methyl, methoxy, acetyl, fluoro, nitrile and nitro groups) and gives the corresponding coupling products in moderate to high yields.
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-19 12:33:14
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCA/article/view/19236
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 57, ##issue.no## 2 (2018): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/19236/58689
http://op.niscair.res.in/index.php/IJCA/article/download/19236/58691
 
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