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Synthesis, crystal structure and properties of a 3D zinc(II) coordination polymer with asymmetric 3-amino-1,2,4-triazolate<p class="Title1"> </p>

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Title Statement Synthesis, crystal structure and properties of a 3D zinc(II) coordination polymer with asymmetric 3-amino-1,2,4-triazolate<p class="Title1"> </p>
 
Added Entry - Uncontrolled Name Fan, Wen Tao ; Yunnan Normal University
Du, Jiao Jiao ; Yunnan Normal University
Xu, Quan Qing ; Yunnan Normal University
Kou, Jun Feng ; Yunnan Normal University
Liu, Feng Yi ; Yunnan Normal University
the National Natural Science Foundation of China (Grant No. 21161023) and Natural Science Foundation of Yunnan Province, China (Grant No. 2009CD048).
 
Uncontrolled Index Term Synthetic and structural inorganic chemistry;Solid state chemistry;Polymers
Coordination polymers, 3D-Framework, X-ray structure, Fluorescence, Zinc sulfate, Triazoles, Symmetric triazoles
 
Summary, etc. <p class="Abstract">A new coordination polymer, [Zn<sub>2</sub>SO<sub>4</sub>(atz)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·(H<sub>2</sub>O)<sub>4</sub> (<strong>1</strong>) (Hatz = 1H-3-amino-1,2,4-triazole) has been synthesized using zinc sulfate and an asymmetric 3-substituted triazole ligand at room temperature. X-ray analysis reveals that complex <strong>1</strong> shows a 3D-framework containing Zn<sub>2</sub>(atz)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>SO<sub>4</sub> subunits, which display a 6-coordinated unimodal pcu topological network. Further, complex <strong>1</strong> exhibits purple fluorescence with an emission maximum at 405 nm in the solid state at room temperature.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-19 14:05:15
 
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http://op.niscair.res.in/index.php/IJCA/article/view/21519
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 57, ##issue.no## 8-9 (2018): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/21519/465467340
http://op.niscair.res.in/index.php/IJCA/article/download/21519/465467342
http://op.niscair.res.in/index.php/IJCA/article/download/21519/465467346
http://op.niscair.res.in/index.php/IJCA/article/download/21519/465470345
http://op.niscair.res.in/index.php/IJCA/article/download/21519/465470347
http://op.niscair.res.in/index.php/IJCA/article/download/21519/465470493
 
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