<p><span>Intermolecular interactions in binary mixtures of phosphonium based ionic liquid and propanoic acid</span></p>
Online Publishing @ NISCAIR
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Authentication Code |
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Title Statement |
<p><span>Intermolecular interactions in binary mixtures of phosphonium based ionic liquid and propanoic acid</span></p> |
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Added Entry - Uncontrolled Name |
Kabane, Bakusele ; Durban University of Technology Rajasekhar, Chokkareddy ; Durban University of Technology Nateshkumar, Bhajanthri ; Durban University of Technology Redhi, Gan G; Durban University of Technology Durban University of Technology |
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Uncontrolled Index Term |
Thermodynamics Solution chemistry, Ionic Liquids, Trihexyltetradecylphosphonium chloride, Propanoic acid, Density, Excess molar volumes, Speeds of sound |
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Summary, etc. |
<p>Thermophysical properties of binary systems containing trihexyltetradecylphosphonium chloride [P<sup>+</sup><sub>14, 6, 6, 6</sub>] [Cl<sup> ̶ </sup>] ionic liquid (IL) and propanoic acid (PA), have been investigated. Measurements of densities and speeds of sound have been made at <em>p</em> = 0.1 MPa and at varying temperatures ranging from 293.15 to 313.15 K. The computed excess properties which include excess molar volume , apparent molar volume ( , intermolecular free length (<em>L</em><sub>f</sub>), isentropic compressibility , apparent molar isentropic compressibility ( ) and deviation in isentropic compressibility have been computed from the experimental data of densities and speeds of sound. Based on the calculated derived properties, it is evident that the investigated IL and PA exhibit strong interactions across the entire mole fraction composition. Good correlation has been achieved with the Redlich-Kister equation.</p> |
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Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2020-10-19 13:04:43 |
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Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/20713 |
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Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 57, ##issue.no## 6 (2018): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
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Language Note |
en |
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Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCA/article/download/20713/63771 http://op.niscair.res.in/index.php/IJCA/article/download/20713/465465353 |
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