Record Details

<p>Hydroxylation of benzene and toluene by heterogeneous iron metal-organic framework (Fe-BTC)</p>

Online Publishing @ NISCAIR

View Archive Info
 
 
Field Value
 
Authentication Code dc
 
Title Statement <p>Hydroxylation of benzene and toluene by heterogeneous iron metal-organic framework (Fe-BTC)</p>
 
Added Entry - Uncontrolled Name BHATTACHARJEE, SAMIRAN ; University of Dhaka
Centre for Advanced Research in Sciences (CARS), University of Dhaka
 
Uncontrolled Index Term Synthetic and structural inorganic chemistry; Solid state chemistry;Polymers, catalysis and analytical chemistry
Catalysis, Liquid phase catalysis, Metal organic frameworks, Hydroxylation, Fe-BTC, Benzene, Toluene
 
Summary, etc. <p>Liquid phase catalytic hydroxylation of benzene and toluene by Fe-containing metal-organic framework (Fe-BTC; BTC = 1,3,5-benzenetricarboxylate) using 30% hydrogen peroxide as an oxidant exhibits good activity and high product selectivity under mild reaction conditions. The effects of temperature, time, substrate/ hydrogen peroxide mole ratio and solvent on catalytic performance are investigated. The catalyst can be reused four times without significant loss of catalytic performance. The hot filtration experiments suggest that hydroxylation reaction occurs on the Fe sites in the MOF matrix. The crystallinity and structure of Fe-BTC remain unchanged during the catalysis reaction, as confirmed by comparison of XRD, FTIR and SEM of the fresh and reused catalyst.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-19 13:04:43
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCA/article/view/19216
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 57, ##issue.no## 6 (2018): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/19216/58610
http://op.niscair.res.in/index.php/IJCA/article/download/19216/58762
 
Terms Governing Use and Reproduction Note Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India© 2015. The Council of Scientific &amp; Industrial Research, New Delhi.