<p><strong>Pyrrolidinedione based Macrocyclic Schiff base complexes</strong><strong>: Synthesis, PXRD, Antimicrobial and DNA binding studies</strong></p>
Online Publishing @ NISCAIR
View Archive InfoField | Value | |
Authentication Code |
dc |
|
Title Statement |
<p><strong>Pyrrolidinedione based Macrocyclic Schiff base complexes</strong><strong>: Synthesis, PXRD, Antimicrobial and DNA binding studies</strong></p> |
|
Added Entry - Uncontrolled Name |
sangwan, vikas |
|
Uncontrolled Index Term |
Template methodology, Macrocycle, DNA binding, Antimicrobial, PXRD |
|
Summary, etc. |
A collection of five macrocyclic complexes of Cd(II), Zn(II), Ni(II), Cu(II) and Co(II) have been synthesized through metal ion template [2+2] cyclocondensation of 1,8-diaminonaphthalene and pyrrolidine-2,5-dione. The newly designed metal complexes have been analyzed by various spectroscopic and physico-analytical techniques like UV-visible, elemental analysis, IR, molar conductance, ESI-MS, EPR, <sup>1</sup>H-NMR and PXRD. The synthesized macrcocyclic metal complexes have been evaluated for their biocidal effects against some strains of pathogenic microbes. The stoichiometry of the macrocyclic complexes has been confirmed with the assistance of molar conductance, ESI-MS and elemental analysis (CHN). DNA interaction studies have been carried out for the elucidation of type and mode of binding of the complexes with the Herring fish sperm DNA. The geometry optimization has been carried out with the help of molecular mechanics using Chem 3D Ultra Software.<br /> |
|
Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2020-10-19 14:05:17 |
|
Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/22232 |
|
Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 57, ##issue.no## 10 (2018): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
|
Language Note |
en |
|
Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCA/article/download/22232/465469521 |
|
Terms Governing Use and Reproduction Note |
Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India© 2015. The Council of Scientific & Industrial Research, New Delhi. |
|