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<p>C-S bond cleavage influenced by metal coordination in Zn(II) bound Schiff base complex: synthesis, structural characterization, catecholase and phenoxazinone synthase activities</p><p> </p>

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Title Statement <p>C-S bond cleavage influenced by metal coordination in Zn(II) bound Schiff base complex: synthesis, structural characterization, catecholase and phenoxazinone synthase activities</p><p> </p>
 
Added Entry - Uncontrolled Name Ghosh, Rajarshi ; The University of Burdwan
PURSE (Govt of India), Department of Higher Education, Science & Technology and Biotechnology, Govt of West Bengal
 
Uncontrolled Index Term Zinc(II), Schiff base, X-ray structure, Catecholase activity, Phenoxazinone synthase activity
 
Summary, etc. <p>A new zinc(II) Schiff base complex (<strong>1</strong>) has been synthesized and X-ray crystallographically characterized. It crystalizes in <em>P2/c</em> space group with monoclinic crystal system. One C-S bond in a (N,S,O) donor organic ligand has been found to be cleaved on reaction with the zinc(II) perchlorate hexahydrate to yield <strong>1 </strong>with new ligand formulation. Complex <strong>1</strong> is found to be both catecholase and phenoxazinone synthase active in MeOH at room temperature. Michaelis-Menten kinetics for each of the activities has been investigated. The turn over numbers for catecholase and phenoxazinone synthase activities are 4.31×10<sup>2</sup> and 5.27×10<sup>5</sup> h<sup>-1</sup>, respectively.</p><p> </p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-10-19 14:05:20
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCA/article/view/20894
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 57, ##issue.no## 11 (2018): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/20894/465464937
http://op.niscair.res.in/index.php/IJCA/article/download/20894/465464938
http://op.niscair.res.in/index.php/IJCA/article/download/20894/465468371
http://op.niscair.res.in/index.php/IJCA/article/download/20894/465468372
 
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