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<p>A green synthesis of isoquinolines using Ru(II)/PEG-400 as homogeneous recyclable catalyst <em>via </em>C-H/N-N bond activation</p>

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Title Statement <p>A green synthesis of isoquinolines using Ru(II)/PEG-400 as homogeneous recyclable catalyst <em>via </em>C-H/N-N bond activation</p>
 
Added Entry - Uncontrolled Name Nakkalwar, Shrinivas L; Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad 431 809, Dist. Nanded, India
Kasralikar, Hanmant M; Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad 431 809, Dist. Nanded, India
Kaminwar, Nitish S; Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad 431 809, Dist. Nanded, India
Patwari, Shivaji B; Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad 431 809, Dist. Nanded, India
Jadhav, Vivekanand B; Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad 431 809, Dist. Nanded, India
 
Uncontrolled Index Term Green synthesis, homogeneous catalyst, biodegradable solvent
 
Summary, etc. <p>A novel and green synthesis of 1-phenyl isoquinoline derivatives has been developed by using Ru(II)/PEG-400 as homogeneous recyclable catalyst <em>via </em>C-H/N-N bond activation <em>via</em> C-H/N-N functionalization of 1-(diphenylmethylene) hydrazine and aryl substituted acetylenes. In order to realize the proposed protocol, Cu(OAc)<sub>2</sub> and AgSbF<sub>6</sub> are used as oxidant and additive respectively in PEG-400 biodegradable solvent. This protocol has a simple extraction procedure, uses biodegradable solvent, affords high atom economy, employs a reusable catalytic system, provides wide substrate scope with high yield of product, for the synthesis of isoquinoline derivatives.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section B (IJC-B)
2020-08-28 12:49:07
 
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http://op.niscair.res.in/index.php/IJCB/article/view/42507
 
Data Source Entry Indian Journal of Chemistry -Section B (IJC-B); ##issue.vol## 59, ##issue.no## 6 (2020): INDIAN JOURNAL OF CHEMISTRY - SECTION B
 
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