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CuI-NPs catalyzed mechanochemical-assisted N-Boc protection of organic amines

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Title Statement CuI-NPs catalyzed mechanochemical-assisted N-Boc protection of organic amines
 
Added Entry - Uncontrolled Name Kamanna, Kantharaju ; Rani Channamma University
UGC-MRP {F.43-181/2014 (SR)}
 
Uncontrolled Index Term Amine protection, CuI-NPs, nanocatalysis, mechanochemical, N-Boc protected amine
 
Summary, etc. A simple, solvent-free, faster and mechanochemical approach for the N-tert-butoxycarbonylation of amines catalyzed by copper iodide nanoparticles as a recyclable catalyst is described. The advantages of this method are simplicity, shorter reaction time (5–15 min), a cost-effective catalyst, and excellent product isolation (82-92%). N-Boc protection of various structurally diverse aliphatic, aromatic, and heterocyclic amines have been carried out with (Boc)2O with 10 mol% catalyst under pestle mortar grinding under solvent-free conditions. The catalyst possesses distinct advantages, ease of handling as well as removal, cleaner reactions, high activity, and environmentally benign. The final product has been characterised by various spectroscopic techniques.
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section B (IJC-B)
2020-11-04 15:59:01
 
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http://op.niscair.res.in/index.php/IJCB/article/view/29856
 
Data Source Entry Indian Journal of Chemistry -Section B (IJC-B); ##issue.vol## 59, ##issue.no## 7 (2020): INDIAN JOURNAL OF CHEMISTRY - SECTION B
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCB/article/download/29856/465491854
http://op.niscair.res.in/index.php/IJCB/article/download/29856/465491896
http://op.niscair.res.in/index.php/IJCB/article/download/29856/465491897
 
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