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<p class="normal" style="text-align: justify;">Nickel(II) complexes of m-ethylphenylxanthate with nitrogen donors and their biological screening</p>

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Title Statement <p class="normal" style="text-align: justify;">Nickel(II) complexes of m-ethylphenylxanthate with nitrogen donors and their biological screening</p>
 
Added Entry - Uncontrolled Name Sharma, Shivangi ; University of Jammu
Sachar, Renu ; Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu 180006, J&K, India
Bajju, G D; Department of Chemistry, University of Jammu, Baba Saheb Ambedkar Road, Jammu 180006, J&K, India
Sharma, Vikas ; Division of Biochemistry, Faculty of Basic Sciences, Sher-e-Kashmir University of Agricultural Sciences and Technology of Jammu, Main Campus Chatha, Jammu 180 009, J&K, India
SKUAST- JAMMU AND IIIM-CSIR JAMMU
 
Uncontrolled Index Term INORGANIC CHEMISTRY
m-Ethylphenylxanthate, Monomeric, Paramagnetic, Pyridine, Thermogravimetric analysis
 
Summary, etc. <p class="normal" style="text-align: justify;">A series of five adducts of m-ethylphenylxanthate of nickel(II) [(m-C<sub>2</sub>H<sub>5</sub>C<sub>6</sub>H<sub>4</sub>OCS<sub>2</sub>)<sub>2</sub>Ni] with nitrogen donors have been synthesized in 1:2 molar ratio by the reaction of aqueous solution of NiCl<sub>2</sub>.6H<sub>2</sub>O with aqueous solution of sodium salt of m-ethylphenylxanthate. These metal complexes are reacted with nitrogen donors to give donor stabilized complex, [(m-C<sub>2</sub>H<sub>5</sub>C<sub>6</sub>H<sub>4</sub>OCS<sub>2</sub>)<sub>2</sub>(L)<sub>2</sub>Ni] where, L= 2-, 3-, 4-ethylpyridine and 2-, 3-chloropyridine. The adducts have been characterized by elemental analysis, molar conductance and magnetic susceptibility measurements, IR, electronic, mass spectral studies, thermogravimetric analysis, powder X-ray diffraction, biological studies. The spectral studies have revealed the octahedral coordination of ligands around Ni(II) metal ion. The adducts are found to be paramagnetic and non-ionic in nature. Mass studies show the monomeric nature of the adducts. The complexes have depicted potential antifungal activity against <em>Bipolaris maydis</em> and <em>Rhizoctonia solani</em>. Some of the synthesized Ni(II) xanthate complexes display <em>in vitro </em>cytotoxic efficacy against human cancer cell lines.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-11-05 10:09:35
 
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http://op.niscair.res.in/index.php/IJCA/article/view/27659
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 59, ##issue.no## 11 (2020): INDIAN JOURNAL OF CHEMISTRY - SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/27659/465494039
http://op.niscair.res.in/index.php/IJCA/article/download/27659/465494040
 
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