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<p>Stereoselective synthesis towards (+)-<em>trans-</em>kumausyne employing vinylogous Mukaiyama type reaction on an α-chloro sulfide</p>

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Title Statement <p>Stereoselective synthesis towards (+)-<em>trans-</em>kumausyne employing vinylogous Mukaiyama type reaction on an α-chloro sulfide</p>
 
Added Entry - Uncontrolled Name Sadagopan, Raghavan ; CSIR-IICT
Chowhan, L Raju ; Department of Organic Synthesis and Process Chemistry, Indian Institute of Chemical Technology, Hyderabad 500 007, India School of Chemistry, University of Hyderabad, Hyderabad 500 046, India
 
Uncontrolled Index Term α-Chloro sulfide, Mukaiyama type reaction, oxa-Michael addition, (+)-trans-Kumausyne, 2-trimethylsiloxy furan.
 
Summary, etc. <p class="Abstract">A stereoselective synthesis towards (+)-<em>trans-</em>kumausyne is disclosed. The key steps of the synthesis include stereoselective C-C formation employing vinylogous Mukaiyama type reaction of an α-chloro sulfide with 2-trimethylsiloxy furan and base-catalyzed isomerization followed by intramolecular oxa-Michael reaction.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section B (IJC-B)
2020-11-09 10:52:30
 
Electronic Location and Access http://op.niscair.res.in/index.php/IJCB/article/view/28078
 
Data Source Entry Indian Journal of Chemistry -Section B (IJC-B); ##issue.vol## 59, ##issue.no## 8 (2020): Indian Journal of Chemistry Section - B (IJCB)
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCB/article/download/28078/465486632
 
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