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<p>Microwave assisted, BF<sub>3</sub>.OEt<sub>2</sub> catalyzed efficient synthesis of tosylhydrazones and SC-XRD study of two of the synthesized tosylhydrazones</p><p> </p>

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Title Statement <p>Microwave assisted, BF<sub>3</sub>.OEt<sub>2</sub> catalyzed efficient synthesis of tosylhydrazones and SC-XRD study of two of the synthesized tosylhydrazones</p><p> </p>
 
Added Entry - Uncontrolled Name Bhuyana, Pubanita ; Department of Chemistry, Rajiv Gandhi University, Rono Hills, Doimukh 791 112, India
Bhuyan, Amar Jyoti; Department of Chemistry, Rajiv Gandhi University, Rono Hills, Doimukh 791 112, India
Bharali, Sourav Jyoti; Department of Chemistry, Rajiv Gandhi University, Rono Hills, Doimukh 791 112, India
Saikia, Lakhinath ; Department of Chemistry, Rajiv Gandhi University, Rono Hills, Doimukh 791 112, India
Dutta, Bidyut Jyoti; Department of Chemistry, Dibrugarh University, Dibrugarh 786 004, India
Department of Science and Technology-Science and Engineering Research Board, India & Council of Scientific and Industrial Research (CSIR), India
 
Uncontrolled Index Term Tosylhydrazones, microwave assisted reaction, BF3.OEt2, carbonyl compounds, tosylhydrazine 
 
Summary, etc. <p class="Abstract"><span lang="EN-GB">A highly efficient methodology for transformation of carbonyl compounds to their corresponding tosylhydrazones under microwave irradiation in presence of BF<sub>3</sub>.OEt<sub>2</sub> catalyst has been developed and described here. The methodology is highly prospective for tosylhydrazone synthesis especially of diaryl ketones, as already existing procedures are found to be less effective for the same. Seventeen carbonyl compounds have been studied and found to deliver their corresponding products in excellent yield (92-98%). The products crystallize out from the reaction mixture during cooling at room temperature which excludes further purification processes. Single crystal X-ray diffraction (SC-XRD) analysis of two of the synthesized tosylhydrazones have been carried out and reported here.</span></p><br /><p> </p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section B (IJC-B)
2020-11-11 11:39:57
 
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http://op.niscair.res.in/index.php/IJCB/article/view/31063
 
Data Source Entry Indian Journal of Chemistry -Section B (IJC-B); ##issue.vol## 59, ##issue.no## 10 (2020): Indian Journal of Chemistry Section - B (IJCB)
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCB/article/download/31063/465495463
 
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