Record Details

<p>P<sub>2</sub>O<sub>5</sub>-mediated Friedel-Crafts acylation of <em>activated </em>arenes with carboxylic <br /> acid as acylating agent</p><p> </p>

Online Publishing @ NISCAIR

View Archive Info
 
 
Field Value
 
Authentication Code dc
 
Title Statement <p>P<sub>2</sub>O<sub>5</sub>-mediated Friedel-Crafts acylation of <em>activated </em>arenes with carboxylic <br /> acid as acylating agent</p><p> </p>
 
Added Entry - Uncontrolled Name Kalshetti, Rupali G; Chemical Engineering and Process Development Division CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India
Mandle, Ram D; Chemical Engineering and Process Development Division CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India
Kamble, Sanjay P; Chemical Engineering and Process Development Division CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India
Sudalai, Arumugam ; Chemical Engineering and Process Development Division CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India
DST, New Delhi (EMR/2016/007030) and CSIR, New Delhi (Emeritus Scheme: 21(1003/16/EMR-II)
 
Uncontrolled Index Term Friedel-Crafts acylations, phosphorus pentoxide, carboxylic acid, 4-methoxyacetophenone
 
Summary, etc. <p>P<sub>2</sub>O<sub>5</sub> has been found to be a highly efficient and environmental friendly catalyst for the liquid-phase acylation of <em>activated</em> aromatic substrates giving aromatic ketones (45-93%) in a regioselective manner. Both aromatic and aliphatic carboxylic acids can be employed as acylating source. The process is particularly demonstrated at 100 g scale in the case of anisole and acetic acid to produce 4-methoxyacetophenone.</p><p> </p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section B (IJC-B)
2020-12-16 14:28:18
 
Electronic Location and Access application/pdf
application/pdf
http://op.niscair.res.in/index.php/IJCB/article/view/29562
 
Data Source Entry Indian Journal of Chemistry -Section B (IJC-B); ##issue.vol## 59, ##issue.no## 12 (2020): Indian Journal of Chemistry Section - B (IJCB)
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCB/article/download/29562/465490873
http://op.niscair.res.in/index.php/IJCB/article/download/29562/465490874
http://op.niscair.res.in/index.php/IJCB/article/download/29562/465490875
 
Terms Governing Use and Reproduction Note Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India© 2015. The Council of Scientific &amp; Industrial Research, New Delhi.