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<p>Heterogeneous catalyst Mn(salicylaldimine) complex covalently bonded to α-titanium phosphate: Synthesis, characterization and catalytic activity for oxidation of cyclohexane</p>

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Title Statement <p>Heterogeneous catalyst Mn(salicylaldimine) complex covalently bonded to α-titanium phosphate: Synthesis, characterization and catalytic activity for oxidation of cyclohexane</p>
 
Added Entry - Uncontrolled Name Khare, Savita ; Devi Ahilya University
Shrivastava, P ; School of Chemical Sciences, Takshashila Campus, Khandwa Road, Devi Ahilya University, Indore (MP) 452 001, India
Kirar, J S; School of Chemical Sciences, Takshashila Campus, Khandwa Road, Devi Ahilya University, Indore (MP) 452 001, India
Parashar, S ; School of Chemical Sciences, Takshashila Campus, Khandwa Road, Devi Ahilya University, Indore (MP) 452 001, India
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Uncontrolled Index Term Catalysis
Catalysts, Heterogeneous catalysts, Oxidation, Titanium phosphate, Cyclohexane, Salicylaldimine, tert-Butylhydroperoxide
 
Summary, etc. <p style="text-align: justify;">A new heterogeneous catalyst, Mn(salicylaldimine) complex covalently bonded to α-titanium phosphate has been synthesized by <em>in situ</em> method and characterized by BET surface area, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, Fourier transform infrared spectra, X-ray photoelectron spectroscopy and inductively coupled plasma atomic emission spectroscopy. The catalytic activity of α-TiP.Mn(salicylaldimine) is studied for the liquid phase oxidation of cyclohexane using <em>tert</em>-butylhydroperoxide as an oxidant under solvent-free condition. In the oxidation reaction, cyclohexane is oxidized to cyclohexanol, cyclohexanone and some unidentified products. A maximum conversion (14.75%) of cyclohexane with 91.70% selectivity of KA-oil is obtained at 353 K after 6 h of reaction time. The catalyst can be reused for four cycles without significant loss of catalytic activity.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2020-12-22 14:56:08
 
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http://op.niscair.res.in/index.php/IJCA/article/view/12250
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 55, ##issue.no## 4 (2016): INDIAN JOURNAL OF CHEMISTRY - SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/12250/35048
http://op.niscair.res.in/index.php/IJCA/article/download/12250/35049
 
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