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<p><span lang="EN-GB">Synthesis, crystal structure and properties of a yttrium complex based on mixed functional ligands</span></p>
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| Authentication Code |
dc |
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| Title Statement |
<p><span lang="EN-GB">Synthesis, crystal structure and properties of a yttrium complex based on mixed functional ligands</span></p> |
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| Added Entry - Uncontrolled Name |
Guan, Lei Jin, Hongzhe ; School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001 Peng, Xiaoming ; School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001 Wang, Ying ; School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001 Xiong, Xuejia ; School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001 |
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| Uncontrolled Index Term |
Synthesis, Yttrium complex, Mixed functional ligand, π-π stacking interactions, Intraligand charge transition |
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| Summary, etc. |
<p style="text-align: justify;"><span lang="EN-GB">A new </span><span lang="EN-GB">yttrium complex, [Y<sub>2</sub>(H<sub>2</sub>Dhbds)<sub>3</sub>(phen)<sub>2</sub>]·[Y<sub>2</sub>(H<sub>2</sub>Dhbds)<sub>2</sub>(H<sub>2</sub>Thbs)(phen)<sub>2</sub>] (<strong>1</strong>) (Na<sub>2</sub>H<sub>2</sub>Dhbds = 4,5-dihydroxy-1,3-benzenedisulfonic acid disodium salt; NaH<sub>3</sub>Thbs = 2,3,5-trihydroxy-1-benzenesulfonic acid sodium salt), has been synthesized and structurally characterized. Complex <strong>1 </strong>consists of two dinuclear structural units bridged by H<sub>2</sub>Dhbds<sup>2-</sup> and H<sub>2</sub>Thbs<sup>2-</sup> ligands, where phen molecules act as N, N-bidentate ligands, chelating Y atoms. The dinuclear structural units are connected by π-π stacking interactions between phen molecules, generating a one-dimensional chain structure. In addition, complex <strong>1</strong> exhibits the broad fluorescent emission band at 365 nm, which originates from intraligand charge transitions. </span></p> |
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| Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2021-01-18 15:11:33 |
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| Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/39048 |
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| Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 60, ##issue.no## 1 (2021): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
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| Language Note |
en |
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| Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCA/article/download/39048/465521477 http://op.niscair.res.in/index.php/IJCA/article/download/39048/465521479 http://op.niscair.res.in/index.php/IJCA/article/download/39048/465521480 http://op.niscair.res.in/index.php/IJCA/article/download/39048/465521547 http://op.niscair.res.in/index.php/IJCA/article/download/39048/465521550 |
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