<p><strong>Effect of triton-X100 on ternary complexes of cobalt (II), nickel(II),copper (II) & zinc(II) with aspartic and citric acids</strong><strong></strong></p>
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Title Statement |
<p><strong>Effect of triton-X100 on ternary complexes of cobalt (II), nickel(II),copper (II) & zinc(II) with aspartic and citric acids</strong><strong></strong></p> |
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Added Entry - Uncontrolled Name |
PEDADA, SRINIVASA RAO ; GAYATHRI VIDYA PARISHED COLLEGE OF ENGINEERING FOR WOMEN NAGESWARA RAO, GOLLAPALLI ; ANDRA UNIVERSITY |
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Uncontrolled Index Term |
STRUCTURAL INORGANIC CHEMISTRY Triton- X 100, stability constants, citric acid, aspartic acid, ternary complexes |
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Summary, etc. |
<p>A computer based investigation has been made pH-metrically on the chemical speciation of mixed ligand complexes in ternary systems consisting of cobalt (II) nickel(II), copper (II) and zinc (II) with aspartic and citric acids in triton- X 100 micellar media. The trend of the variation in the stability constants with changing dielectric constant as well as mole fraction of the medium is explained based on the electrostatic interactions of the side chains of the ligands, charge neutralization, chelate effect, stacking interactions and hydrogen bonding. The existence of different ternary species is established from modelling studies using the computer program MINIQUAD75. Distribution diagrams with pH at different compositions of surfactant and structures of plausible ternary complexes are presented.</p> |
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Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2021-02-25 16:31:05 |
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Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/32300 |
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Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 60, ##issue.no## 2 (2021): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
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Language Note |
ENGISH |
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Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCA/article/download/32300/465499768 http://op.niscair.res.in/index.php/IJCA/article/download/32300/465499769 http://op.niscair.res.in/index.php/IJCA/article/download/32300/465499770 |
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