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Electron transfer study on newly synthesized Ti(IV)/Zr(IV) complexes of amide and oxime functionality: A pulse radiolytic and theoretical revelation

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Title Electron transfer study on newly synthesized Ti(IV)/Zr(IV) complexes of amide and oxime functionality: A pulse radiolytic and theoretical revelation
 
Creator Thomas, Raji
Jose, Densely
Joseph, Nelson P
Pardasani, R T
Mukherjee, T
 
Subject Ti(IV)/Zr(IV) complex
Oxime complex
Amide complex
Hydrated electron
Pulse radiolysis
 
Description 361-369
Complexes of the general formula Cp2Ti(IV)L, Cp2Zr(IV)L, Cp2Ti(IV)L1 and Cp2Zr(IV)L1 have been synthesized with N,N’-bis(2-pyridyl)pyridine-2,6-dicarboxamide (H2L) and 9,10-phenanthrenequinone dioxime (H2L1). The complexes have been characterized by different spectral techniques and their reduction reactions have been carried out with hydrated electron as reducing radical, mechanism which has been explored pulse radiolytically. Theoretical calculations have been performed to understand the effect of chelation and electron transfer processes in complexes.
 
Date 2021-03-03T04:14:26Z
2021-03-03T04:14:26Z
2021-03
 
Type Article
 
Identifier 0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/56378
 
Language en_US
 
Rights CC Attribution-Noncommercial-No Derivative Works 2.5 India
 
Publisher NISCAIR-CSIR, India
 
Source IJC-A Vol.60A(03) [March 2021]