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Determination and correlation of solubility and solution thermodynamics of 1, 2-diphenylethane in different pure solvents

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Title Determination and correlation of solubility and solution thermodynamics of 1, 2-diphenylethane in different pure solvents
 
Creator Qi, Yabing
 
Subject 1, 2-Diphenylethane
Correlation
Solubility
Thermodynamics
 
Description 117-122
The correlation of solubility and solution thermodynamics of 1,2- diphenylethane in different pure solvents has been studied. The mole fraction solubilities of 1, 2-diphenylethane in acetone, chloroform, dichloromethane, and ethanol increase with temperature. The mole fraction solubility in acetone, chloroform and dichloromethaneare much higher than that in ethanol and the mole fraction solubilities in chloroform and dichloromethane are higher than that in acetone. The solubility data were well correlated by the modified Apelblat,the semi-empirical Buchowski-Ksiazczak λh equation, and the ideal solution equation.The enthalpy, entropy and apparent free Gibbs energy of solution in different solvents were calculated. The dissolving process of 1,2-diphenylethane was endothermic, entropy-driving and not spontaneous.
 
Date 2021-03-16T10:35:30Z
2021-03-16T10:35:30Z
2021-01
 
Type Article
 
Identifier 0975-0991 (Online); 0971-457X (Print)
http://nopr.niscair.res.in/handle/123456789/56524
 
Language en_US
 
Rights CC Attribution-Noncommercial-No Derivative Works 2.5 India
 
Publisher NISCAIR-CSIR, India
 
Source IJCT Vol.28(1) [January 2021]