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Efficient and region-selective conversion of octanes to epoxides under ambient conditions: Performance of tri-copper catalyst, [Cu3I(L)]+1 (L=7-N-Etppz)

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Title Efficient and region-selective conversion of octanes to epoxides under ambient conditions: Performance of tri-copper catalyst, [Cu3I(L)]+1 (L=7-N-Etppz)
 
Creator Nagababu, Penumaka
Paul, Perala Sudheer
Reddy, Thatiparthi Byragi
Krupadam, Reddithota J
 
Subject Epoxidation
Region-selectivity
Ambient conditions
Tri-copper catalyst
 
Description 742-745
In this paper, is described the conversion of the octane group of hydrocarbons into industrially important epoxides using tri-copper catalyst, [Cu3I(L)]+1 (L=7-N-Etppz). The role of hydrogen peroxide as a sacrificial oxygen donor during catalytic conversion to epoxides has been investigated. The performance of the catalyst has been evaluated in terms of turnover numbers (TON) and turnover frequencies (TOF) reported in this article.
 
Date 2021-06-25T07:34:31Z
2021-06-25T07:34:31Z
2021-05
 
Type Article
 
Identifier 0975-0983(Online); 0376-4699(Print)
http://nopr.niscair.res.in/handle/123456789/57584
 
Language en_US
 
Rights CC Attribution-Noncommercial-No Derivative Works 2.5 India
 
Publisher NISCAIR-CSIR, India
 
Source IJC-B Vol.60B(05) [May 2021]