Record Details

<p>Mo- and W-containing layered double hydroxides: Mild and selective oxidation of alkenes with H<sub>2</sub>O<sub>2</sub></p>

Online Publishing @ NISCAIR

View Archive Info
 
 
Field Value
 
Authentication Code dc
 
Title Statement <p>Mo- and W-containing layered double hydroxides: Mild and selective oxidation of alkenes with H<sub>2</sub>O<sub>2</sub></p>
 
Added Entry - Uncontrolled Name Agarwalla, Uday Sankar; Department of Chemistry, P D Women’s College, Jalpaiguri, West Bengal 735 101, India
University Grants Commission
 
Uncontrolled Index Term Catalysis
Layered double hydroxide, Hydrotalcite, Polyoxometalate, Alkene, Oxidation, Hydrogen peroxide
 
Summary, etc. <p style="text-align: justify;">Molybdenum- and tungsten-containing (M<sub>7</sub>O<sub>24</sub><sup>6-</sup>, M = Mo or W) layered double hydroxides (LDHs) with Mg<sup>2+</sup> and Al<sup>3+</sup> cations in the brucite-like layer have been prepared by direct anion exchange, starting from the corresponding terephthalate precursor. The solids have been characterized by various instrumental techniques such as elemental chemical analysis, powder X-ray diffraction, infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and thermogravimetric analysis. The M<sub>7</sub>O<sub>24</sub><sup>6- </sup>intercalated LDHs have been explored as catalysts for the selective oxidation of a series of alkenes at room temperature using safer, inexpensive and environmentally benign hydrogen peroxide as oxidant. Reaction conditions have been optimized considering different reaction parameters to achieve maximum conversion in the catalytic oxidation reaction. Recycling of the catalyst has shown that it can be reused up to three more cycles without significant loss of performance.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2021-07-01 12:48:51
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCA/article/view/42530
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 60, ##issue.no## 5 (2021): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/42530/465534874
http://op.niscair.res.in/index.php/IJCA/article/download/42530/465534875
http://op.niscair.res.in/index.php/IJCA/article/download/42530/465535050
http://op.niscair.res.in/index.php/IJCA/article/download/42530/465535051
 
Terms Governing Use and Reproduction Note Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India© 2015. The Council of Scientific &amp; Industrial Research, New Delhi.