ICAR Research Data Repository for Knowledge Management
<p>Synthesis, crystal structure and thermolysis kinetics of [Co(H<sub>2</sub>O)<sub>6</sub>](ClO<sub>4</sub>)<sub>2</sub>.(HMTA)<sub>2</sub>.2H<sub>2</sub>O (HMTA = hexamethylenetetramine)</p>
Online Publishing @ NISCAIR
View Archive Info| Field | Value | |
| Authentication Code |
dc |
|
| Title Statement |
<p>Synthesis, crystal structure and thermolysis kinetics of [Co(H<sub>2</sub>O)<sub>6</sub>](ClO<sub>4</sub>)<sub>2</sub>.(HMTA)<sub>2</sub>.2H<sub>2</sub>O (HMTA = hexamethylenetetramine)</p> |
|
| Added Entry - Uncontrolled Name |
Singh, Chandra Prakash; Department of Chemistry, D B S College, Kanpur, U P 208 006, India Singh, Abhishek ; Department of Chemistry, D B S College, Kanpur, U P 208 006, India Nibha, Nibha ; Department of Chemistry, D D U Gorakhpur University, Gorakhpur, U P 273 009, India Daniliuc, Constantin G; Organisch Chemisches Institut, Universität Münster, Germany Kumar, Bharat ; Department of Chemistry, M V College, Buxar, Bihar 802 101, India Singh, Gurdip ; Department of Chemistry, D D U Gorakhpur University, Gorakhpur, U P 273 009, India RAO, DEVENDRA PRATAP; Department of Chemistry, D A V P G College, Kanpur, U P 208 001, India UGC NEW DELHI INDIA |
|
| Uncontrolled Index Term |
Synthetic and structural inorganic chemistry Cobalt, crystal structure, DSC, DTA, thermal analysis. |
|
| Summary, etc. |
<p style="text-align: justify;">A new compound, [Co(H<sub>2</sub>O)<sub>6</sub>](ClO<sub>4</sub>)<sub>2</sub>.(HMTA)<sub>2</sub>.2H<sub>2</sub>O; HMTA = hexamethylenetetramine) has been synthesized and characterized with the assistance of X-ray crystallography, elemental analysis, FT-IR spectroscopy, TG-DTA and DSC (N<sub>2 </sub>atmosphere). Both TG data model-fitting method as well as method of model free isoconversional have been employed to observe the kinetics of thermolysis of the compound. In order to understand the effect of sudden high heat, measurements of explosion delay are undertaken at regular five unique temperatures and the kinetics of explosion has also been explored using Arrhenius equation.</p> |
|
| Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2021-07-01 12:48:51 |
|
| Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/40587 |
|
| Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 60, ##issue.no## 5 (2021): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
|
| Language Note |
en |
|
| Nonspecific Relationship Entry |
http://op.niscair.res.in/index.php/IJCA/article/download/40587/465526933 |
|
| Terms Governing Use and Reproduction Note |
Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India© 2015. The Council of Scientific & Industrial Research, New Delhi. |
|