<p><strong>Electron transfer study on newly synthesized Ti(IV)/Zr(IV) complexes of amide and oxime functionality: A pulse radiolytic and theoretical revelation </strong></p>
Online Publishing @ NISCAIR
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dc |
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Title Statement |
<p><strong>Electron transfer study on newly synthesized Ti(IV)/Zr(IV) complexes of amide and oxime functionality: A pulse radiolytic and theoretical revelation </strong></p> |
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Added Entry - Uncontrolled Name |
Thomas, Raji |
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Summary, etc. |
<p>Complexes of the general formula Cp<sub>2</sub>Ti(IV)L, Cp<sub>2</sub>Zr(IV)L, Cp<sub>2</sub>Ti(IV)L<sup>1</sup> and Cp<sub>2</sub>Zr(IV)L<sup>1</sup> have been synthesized with N, N’-bis(2-pyridyl)pyridine-2,6-dicarboxamide(H<sub>2</sub>L) and 9, 10-phenanthrenequinone dioxime (H<sub>2</sub>L<sup>1</sup>). The complexes have been characterized by different spectral techniques and their reduction reactions were carried out with hydrated electron as reducing radical, mechanism has been explored pulse radiolytically. Theoretical calculations have been performed to understand the effect of chelation and electron transfer processes in complexes.</p> |
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Publication, Distribution, Etc. |
Indian Journal of Chemistry -Section A (IJCA) 2021-07-01 11:37:05 |
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Electronic Location and Access |
application/pdf http://op.niscair.res.in/index.php/IJCA/article/view/39627 |
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Data Source Entry |
Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 60, ##issue.no## 3 (2021): INDIAN JOURNAL OF CHEMISTRY- SECTION A |
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Language Note |
en |
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Nonspecific Relationship Entry |
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