Record Details

<p>Synthesis, structure and molecular Hirshfeld surface analysis of polymeric cadmium(II) complex involving tetradentate N<sub>3</sub>S-donor ligand and dicyanamide as bridging ligand</p>

Online Publishing @ NISCAIR

View Archive Info
 
 
Field Value
 
Authentication Code dc
 
Title Statement <p>Synthesis, structure and molecular Hirshfeld surface analysis of polymeric cadmium(II) complex involving tetradentate N<sub>3</sub>S-donor ligand and dicyanamide as bridging ligand</p>
 
Added Entry - Uncontrolled Name Kumar, Sujit Baran; Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara 390 002, India
Munshi, Sadeka J; Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara-390002, Gujarat
Sadhu, Mehul H; Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara-390002, India, Present address: Department of Chemistry Government science college, Idar, Sabarkantha, Gujarat, India
Guin, Mridula ; Department of Chemistry and Biochemistry, Sharda University, Greater Noida, India.
Financial support to the Department of Chemistry, The Maharaja Sayajirao University of Baroda from UGC CASII, UGC, New Delhi,
 
Uncontrolled Index Term Synthetic and structural inorganic chemistry
Cadmium(II), N3S-donor ligand, Bridging ligand, Polymeric complex, Hirshfeld surface analysis
 
Summary, etc. <p style="text-align: justify;">One new polymeric cadmium(II) complex {[Cd(bdmpe)(µ<sub>1,5</sub>-dca)]ClO<sub>4</sub>.CH<sub>3</sub>OH}<sub>n </sub>has been synthesized by the reaction of cadmium perchlorate with ligand <em>N,N</em>-bis((3,5-dimethyl-<em>1H</em>-pyrazol-1-yl)methyl)-2- phenylthio)ethan-1-amine (bdmpe) in presence of dca (dicyanamide, N(CN)<sub>2</sub><sup>-</sup>) as bridging ligand in methanol and characterized by spectroscopic techniques. Single crystal X-ray diffraction study of the complex confirmed that it has polymeric 1D chain and each cadmium centre has distorted octahedral geometry with N<sub>5</sub>S coordination and is bonded through two terminal nitrile group of the dca ligand using m<sub>1,5</sub> coordination modes. Intermolecular interactions and packing modes of the compound are described by Hirshfeld surface analysis and two dimensional finger print plots.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2021-07-01 12:48:51
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJCA/article/view/42178
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 60, ##issue.no## 5 (2021): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/42178/465533495
http://op.niscair.res.in/index.php/IJCA/article/download/42178/465533496
http://op.niscair.res.in/index.php/IJCA/article/download/42178/465533497
http://op.niscair.res.in/index.php/IJCA/article/download/42178/0
http://op.niscair.res.in/index.php/IJCA/article/download/42178/465533498
http://op.niscair.res.in/index.php/IJCA/article/download/42178/465534328
http://op.niscair.res.in/index.php/IJCA/article/download/42178/465534329
http://op.niscair.res.in/index.php/IJCA/article/download/42178/465534330
 
Terms Governing Use and Reproduction Note Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India© 2015. The Council of Scientific &amp; Industrial Research, New Delhi.