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<p style="text-align: justify;">Synthesis of 4-{(<em>E</em>)-[(3-methyl-5-sulphanyl-4H-1,2,4-triazol-4-yl)imino]methyl} benzaldehyde and its complexes with Ag(I), Hg(II), Zn(II), Co(II), Ni(II) ions and its characterisation</p>

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Title Statement <p style="text-align: justify;">Synthesis of 4-{(<em>E</em>)-[(3-methyl-5-sulphanyl-4H-1,2,4-triazol-4-yl)imino]methyl} benzaldehyde and its complexes with Ag(I), Hg(II), Zn(II), Co(II), Ni(II) ions and its characterisation</p>
 
Added Entry - Uncontrolled Name Prasad, Ashwini ; Saint Aloysius College
N, Gopalakrishna Bhat; Srinivas Institute of Technology, Valachil, Mangaluru, Karnataka 575 001, India
Nazareth, Ronald A; St Aloysius College, Mangaluru, Karnataka 575 001, India
 
Uncontrolled Index Term Analytical Chemistry
MSTB, Ag(I), Hg(II), Cu(II), Ni(II), Co(II) complex, ML2(H2O)2, Terephthaldehyde  
 
Summary, etc. <p style="text-align: justify;">A novel Schiff base 4-{(E)-[(3-methyl-5-sulphanyl-4H-1,2,4-triazol-4-yl)imino]methyl}benzaldehyde (MSTB) and its complexes with Ag(I), Hg(II), Cu(II), Ni(II) and Co(II) have been prepared. MSTB is prepared by the condensation reaction between triazole and terephthaldehyde. In complexes, MSTB molecules are found to link with the metal ion, through thiolsulphur after deprotonation and the nitrogen of the azomethine group. The composition of the complexes are found to be ML where M =Ag, ML<sub>2</sub> where M=Zn, Hg and ML<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub> where M= Co, Ni. Linear polymeric structure is proposed for Ag(I) complex, tetrahedral structure is proposed for Zn(II) and Hg(II) complexes and octahedral structure is proposed for Co(II) and Ni(II) complexes.</p> <p> </p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2021-07-01 12:48:51
 
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http://op.niscair.res.in/index.php/IJCA/article/view/42321
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 60, ##issue.no## 5 (2021): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/42321/465534563
http://op.niscair.res.in/index.php/IJCA/article/download/42321/465534564
 
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