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A new hybrid iron fluoride bipyridine with mixed valence: Fe<sub>2</sub>F<sub>5</sub>(2,2'-bipyridine)<sub>2</sub>H<sub>2</sub>O

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Title Statement A new hybrid iron fluoride bipyridine with mixed valence: Fe<sub>2</sub>F<sub>5</sub>(2,2'-bipyridine)<sub>2</sub>H<sub>2</sub>O
 
Added Entry - Uncontrolled Name Smida, Mouna ; Laboratoire de Chimie Inorganique, Faculté des Sciences de Sfax, Département de Chimie, Université de Sfax, BP 1171, 3000 Sfax, Tunisie
Dammak, Mohamed ; Laboratoire de Chimie Inorganique, Faculté des Sciences de Sfax, Département de Chimie, Université de Sfax, BP 1171, 3000 Sfax, Tunisie
Garcia-Granda, Santiago ; Département de Chimie et Physique Analytique, Faculté de Chimie, Université d’Oviedo-CINN, 33006 Oviedo, Espagne
 
Uncontrolled Index Term Coordination chemistry, Hydrothermal synthesis, X-ray diffraction, Inorganic-organic hybrid compounds, Crystal structure, Hybrid compounds, Thermal analysis, Iron, Fluoroferrates, Metal organic framwork
 
Summary, etc. <p style="text-align: justify;">Hydrothermal synthesis of iron fluoride compound, Fe<sub>2</sub>F<sub>5</sub>(2,2'-bipyridine)<sub>2</sub>H<sub>2</sub>O, and its characterization by single crystal X-ray diffraction is reported. The compound is found to crystallize in the triclinic space group . The monohydrate fluoroferrate of bipyridine is built up from Fe<sub>4</sub>F<sub>10</sub>N<sub>8</sub> tetrahedron connected by eight nitrogen atoms of four 2,2'-bipyridine molecules and separated by H<sub>2</sub>O molecules. The main feature of this atomic arrangement is the coexistence of two oxidation states of iron cations and hybrid class II with 0-D dimensionality. Thermal and IR spectral analysis have been carried out for the title compound to confirm the hematite compound as residual and the presence of organic molecule , respectively. Magnetic characterization does not reveal any ferromagnetic component in the range of magnetic field from -20 kOe to 20 kOe at room temperature.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2021-07-02 10:20:01
 
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http://op.niscair.res.in/index.php/IJCA/article/view/10736
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 55, ##issue.no## 7 (2016): INDIAN JOURNAL OF CHEMISTRY - SECTION A
 
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Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/10736/30207
 
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