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Nickel(II) chelates with N-phenethyl-iminodiacetate(2-)-like ligands: Synthesis, crystal structure and spectroscopic studies

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Title Nickel(II) chelates with N-phenethyl-iminodiacetate(2-)-like ligands: Synthesis, crystal structure and spectroscopic studies
 
Creator Patel, Dheerendra Kumar
Choquesillo-Lazarte, Duane
Domínguez-Martín, Alicia
González-Pérez, Josefa María
Niclós-Gutiérrez, Juan
 
Subject Nickel(II)
Metal-chelate
Iminodiacetate derivatives
Crystal structure
 
Description 806-811
The stoichiometric reactions between Ni(II) hydroxy-carbonates and N-p-(R)-H2pheida derivatives (R = MeO or F for MOpheida or Fpheida, respectively) yield two binary compounds [Ni(MOpheida)(H2O)3] (1) and [Ni(Fpheida)(H2O)3] (2). The crystal of compounds 1 and 2 are iso-type; space group P21/c. Our crystallographic results revealed that both studied metal-chelates have molecular structure and the used p-R substituents on the pheida skeleton yield the same structural features. The IDA moiety of pheida-like ligands exhibit the fac-NO2 conformation (1 & 2). Crystal structure of H2Fpheida free acid have also been reported herein.
 
Date 2021-07-05T11:37:26Z
2021-07-05T11:37:26Z
2021-06
 
Type Article
 
Identifier 0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/57620
 
Language en
 
Publisher CSIR-NIScPR, India
 
Source JC-A Vol.60A(06) [June 2021]