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<p style="text-align: justify;"><strong>Nickel(II) chelates with N-phenethyl-iminodiacetate(2-)-like ligands: Synthesis, crystal structure and spectroscopic studies.</strong></p>

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Title Statement <p style="text-align: justify;"><strong>Nickel(II) chelates with N-phenethyl-iminodiacetate(2-)-like ligands: Synthesis, crystal structure and spectroscopic studies.</strong></p>
 
Added Entry - Uncontrolled Name Patel, Dheerendra Kumar; Barkatulla University Bhopal
Choquesillo-Lazarte, Duane ; Laboratorio de Estudios Cristalográficos, IACT-CSIC, P.T. Ciencias de la Salud, Granada, Spain
Domínguez-Martín, Alicia ; University of Granada, E-18071 Granada, Spain
González-Pérez, Josefa María ; University of Granada, E-18071 Granada, Spain
Niclós-Gutiérrez, Juan ; University of Granada, E-18071 Granada, Spain
Financial support of Junta de Andalucía (FQM-283 Research Group) and Factoría de Cristalización-LEC are acknowledged. DKP thanks to AECID for a pre-doctoral grant and University of Granada for his stay at Prof Juan Niclós-Gutiérrez research group.
 
Uncontrolled Index Term Solid state chemistry; Bio-inorganic chemistry;
Nickel(II), iminodiacetate derivatives, metal-chelate, crystal structure
 
Summary, etc. <p style="text-align: justify;">The stoichiometric reactions between Ni(II) hydroxy-carbonates and N-<em>p</em>-(R)-H<sub>2</sub>pheida derivatives (R =  MeO or F for  MOpheida or Fpheida respectively) yield two novel binary compounds [Ni(MOpheida)(H<sub>2</sub>O)<sub>3</sub>] (<strong>1</strong>) and [Ni(Fpheida)(H<sub>2</sub>O)<sub>3</sub>] (<strong>2</strong>). The crystal of compounds <strong>1</strong> and <strong>2</strong> are iso-type; space group P2<sub>1</sub>/c. Our crystallographic results revealed that both studied metal-chelates have  molecular structure and the used p-R substituents on the pheida skeleton yield the same structural features. The IDA moiety of pheida-like ligands exhibit the <em>fac</em>-NO<sub>2</sub> conformation (<strong>1</strong> &amp; <strong>2</strong>). Crystal structure of H<sub>2</sub>Fpheida free acid have also been reported herein.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section A (IJCA)
2021-09-22 10:23:28
 
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http://op.niscair.res.in/index.php/IJCA/article/view/44600
 
Data Source Entry Indian Journal of Chemistry -Section A (IJCA); ##issue.vol## 60, ##issue.no## 6 (2021): INDIAN JOURNAL OF CHEMISTRY- SECTION A
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCA/article/download/44600/465542287
http://op.niscair.res.in/index.php/IJCA/article/download/44600/465542410
http://op.niscair.res.in/index.php/IJCA/article/download/44600/465542411
http://op.niscair.res.in/index.php/IJCA/article/download/44600/465542412
 
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