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<p>Rational design and expeditious synthesis of aromatic cyanodienone derivatives assisted by cyanide-halide exchange</p><br />

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Title Statement <p>Rational design and expeditious synthesis of aromatic cyanodienone derivatives assisted by cyanide-halide exchange</p><br />
 
Added Entry - Uncontrolled Name zeraatpisheh, fatemeh ; Department of Chemistry, Behbahan Khatam Alanbia University of Technology, Behbahan, Iran
Abadast, Fatemeh ; Department of Chemistry, Behbahan Khatam Alanbia University of Technology, Behbahan, Iran
Shahmorad, Maryam ; Department of Chemistry, Behbahan Khatam Alanbia University of Technology, Behbahan, Iran
Department of Chemistry, Behbahan Khatam Alanbia University of Technology, Behbahan, Iran
 
Uncontrolled Index Term Cyanodienone, triarylpyrylium perchlorate, 1-n-butyl-3-methylimidazolium cyanide, cyanide-halide exchange, environmentally friendly methodology, ionic liquid
 
Summary, etc. <p>1-<em>n</em>-Butyl-3-methylimidazolium cyanide ([bmim]CN), in the presence of [bmim]Br has been prepared and used for the first time as the medium as well as reagent for the synthesis of aromatic cyanodienones from the corresponding triarylpyrylium perchlorates by cyanide-halide exchange. The [bmim]CN having a reactive anion, is an accelerated reaction technique without external solvent and renders the whole synthesis into a truly eco-friendly protocol. The products can be isolated without aqueous work-up in high purity and excellent yield.</p><p> </p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry -Section B (IJC-B)
2021-10-05 10:39:28
 
Electronic Location and Access application/pdf
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http://op.niscair.res.in/index.php/IJCB/article/view/29686
 
Data Source Entry Indian Journal of Chemistry -Section B (IJC-B); ##issue.vol## 60, ##issue.no## 7 (2021): Indian Journal of Chemistry- Section-B, (IJCB)
 
Language Note en
 
Nonspecific Relationship Entry http://op.niscair.res.in/index.php/IJCB/article/download/29686/465491361
 
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