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Efficiency of single and di- site phase transfer catalyzed polymerization of glycidyl methacrylate in the two-phase system: A kinetic study

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Title Efficiency of single and di- site phase transfer catalyzed polymerization of glycidyl methacrylate in the two-phase system: A kinetic study
 
Creator Meena, M
Umapathy, M J
Yoganand, K S
 
Subject Free Radical Polymerization
Kinetics
Mechanism
Phase Transfer Catalyst
Rate of Polymerization
 
Description 445-452
In the present kinetic study, glycidyl methacrylate has been polymerized using synthesized single-site phase transfer catalyst - 2-benzoylethyldecyldimethylammonium bromide and di-site –phase transfer catalyst -1,1,4,4-tetramethyl-1,4 dioctylethylenediammonium bromide along with potassium peroxydisulfate as the initiator in inert medium and at a constant temperature of 60°C. The effect of concentrations of the monomer, initiator, catalyst, ionic strength, pH and solvent polarity on the rate of polymerization has been examined. The order with respect to the monomer, initiator, and phase transfer catalyst was found to be 1, 0.5, and 0.5, respectively. A suitable polymerization mechanism is proposed. Ionic strength and pH has no impact on the rate of polymerization. It is observed that, as the solvent's polarity increased, the rate of polymerization also increased. Di-site phase transfer catalyst results in a higher rate of polymerization compared with single-site phase transfer catalyst while polymerizing glycidyl methacrylate.
 
Date 2021-10-13T06:27:32Z
2021-10-13T06:27:32Z
2021-07
 
Type Article
 
Identifier 0975-0991 (Online); 0971-457X (Print)
http://nopr.niscair.res.in/handle/123456789/58272
 
Language en
 
Publisher NIScPR-CSIR, India
 
Source IJCT Vol.28(4) [July 2021]