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Lewis acid promoted synthesis of methylene-bridged α-and γ-bis-benzopyrones

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Field Value
 
Title Lewis acid promoted synthesis of methylene-bridged α-and γ-bis-benzopyrones
 
Creator Kumar, Sandeep
Prasad, Ashok K
Mehta, Shilpika Bali
 
Subject O-Methoxyacetyl derivatives of hydroxyl-chromanones
coumarins and chromones
Lewis acid
methylenebridged bis-benzopyrones
Fries rearrangement
 
Description 43-50
The Lewis acid promoted Fries rearrangement of O-methoxyacetyl derivatives of hydroxy-chromanones, coumarins and
chromones under solvent-free condition gives isomeric methylene-bridged bischromanones, biscoumarins and
bischromones, respectively, in good yields. The benzopyrone precursors undergo intermolecular rearrangement wherein two
benzopyrone moieties are joined through their benzene rings via an un-substituted methylene bridge.
 
Date 2022-02-01T11:42:12Z
2022-02-01T11:42:12Z
2022-01
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscair.res.in/handle/123456789/59040
 
Language en
 
Publisher NIScPR-CSIR, India
 
Source IJC Vol.61(01) [January 2022]