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Heterocyclic ligated Co(II), Ni(II), Cu(II) and Zn(II) complexes for efficient photocatalytic and biological applications

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Title Heterocyclic ligated Co(II), Ni(II), Cu(II) and Zn(II) complexes for efficient photocatalytic and biological applications
 
Creator Joseyphus, R Selwin
R, Reshma
Arish, D
 
Subject Indal
Photocatalytic
Schiff base
Antimicrobial
 
Description 263-277
We report the synthesis and characterization techniques of mononuclear, heterocyclic ligated Co(II), Ni(II), Cu(II) and
Zn(II) complexes. These heterocyclic derivatives, Schiff base (indal-2-abu), are obtained from the reaction between indole-
3-carboxaldehyde (indal) and 2-aminobutyric acid (2-abu). From the fundamental analysis, it has been found that the Schiff
base with the aforementioned metal ions forms four coordinated mononuclear complexes on 1:2 (metal:ligand)
stoichiometry. The structural changes of the complexes are analyzed by FT-IR, electronic and magnetic analysis. The
photocatalytic dye degradation activity study of the compounds is performed under UV-light using methylene blue (MB)
dye. All the complexes are found to be excellent catalysts for the degradation of MB. Molecular docking is used to
recognize the energetic site of the receptor, and attain the finest geometry of the ligand-receptor complex. Furthermore,
antimicrobial investigations of Schiff base and its complexes are tested and the results are discussed in detail.
 
Date 2022-03-23T10:28:55Z
2022-03-23T10:28:55Z
2022-03
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscair.res.in/handle/123456789/59345
 
Language en
 
Publisher NIScPR-CSIR, India
 
Source IJC Vol.61(03) [March 2022]