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<p style="text-align: justify;">Syntheses, spectral characterization and antidiabetic activities of oxidovanadium(V) complexes with bi-and tridentate ligands</p>

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Title Statement <p style="text-align: justify;">Syntheses, spectral characterization and antidiabetic activities of oxidovanadium(V) complexes with bi-and tridentate ligands</p>
 
Added Entry - Uncontrolled Name Patel, Neetu ; Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara 390 002, India
Patel, A K ; Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara 390 002, India
Prajapati, A K ; Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara 390 002, India
Jadeja, R N ; Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara 390 002, India
 
Uncontrolled Index Term Oxidovanadium(V) complexes, Aroylhydrazone ligand, Density functional Theory, Antidiabetic activity
 
Summary, etc. <p style="text-align: justify;">Four new oxidovanadium(V) complexes [VO(L<sup>1</sup>)(Mol)] (<strong>1</strong>), [VO(L<sup>2</sup>)(Mol)] (<strong>2</strong>), [VO(L<sup>3</sup>)(Mol)] (<strong>3</strong>) and [VO(L<sup>4</sup>)(Mol)] (<strong>4</strong>) (where L<sup>1</sup>-L<sup>4</sup> = aroylhydrazones and Mol = maltol) have been synthesized with different ligands. The complexes have been characterized using microanalysis, spectral fab mass, UV-visible, electrochemical (cyclic voltammetry and differential pulse voltammetry), density functional theory calculations have been performed to predict the optimized geometry, global reactivity parameters and electron density. In these complexes, the d-d absorption band is not observed as being d<sup>0</sup> vanadium centres in these complexes. The electrochemical behaviour of these complexes are explored by cyclic voltammetry and differential pulse voltammetry (DPV). All complexes exhibit one electron transfer i.e., reduction of vanadium(V) to vanadium(IV). These complexes are screened for <em>in vitro</em> α-glucosidase and α-amylase inhibition study. Complex <strong>3</strong> has an interesting insulin-like activity.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry (IJC)
2022-03-24 15:14:48
 
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http://op.niscair.res.in/index.php/IJC/article/view/61714
 
Data Source Entry Indian Journal of Chemistry (IJC); ##issue.vol## 61, ##issue.no## 3 (2022): Indian Journal of Chemistry-(IJC)
 
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