Hydrogen bonded molecular rectangle of N,N-bis(3-quinolyl- methylene)diphenylethanedionedihydrazone
NOPR - NISCAIR Online Periodicals Repository
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Title |
Hydrogen bonded molecular rectangle of N,N-bis(3-quinolyl- methylene)diphenylethanedionedihydrazone
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Creator |
Patra, Goutam K
Manna, Amit K De, Dinesh |
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Subject |
Hydrazone
quinoline 3-carboxaldehyde single-crystal X-ray - stacking interactions supramolecules |
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Description |
416-419
The title compound, N,N-bis (3-quinolylmethylene) diphenylethanedionedihydrazone (I) (molecular formula, C34H24N6) has been synthesized by the reaction of quinoline 3-carboxaldehyde and diphenylethanedionedihydrazone in 2:1 molar ratio. The molecular structure has been characterized by room-temperature single-crystal X-ray diffraction which reveals that two quinoline moieties are disposed nearly perpendicularly around the central C-C bond giving an ‘L’ shape to the molecule. This particular geometry gives rise to the hydrogen bonded supramolecular rectangle of two self-complementary molecules. These supramolecular units are further assembled by - interaction. |
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Date |
2022-04-19T06:27:44Z
2022-04-19T06:27:44Z 2022-04 |
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Type |
Article
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Identifier |
2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscair.res.in/handle/123456789/59542 |
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Language |
en
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Publisher |
NIScPR-CSIR, India
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Source |
IJC Vol.61(04) [April 2022]
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