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<p>Hydrogen bonded molecular rectangle of <em>N</em>,<em>N</em><em>¢</em>-bis(3-quinolyl- methylene)diphenylethanedionedihydrazone</p>

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Title Statement <p>Hydrogen bonded molecular rectangle of <em>N</em>,<em>N</em><em>¢</em>-bis(3-quinolyl- methylene)diphenylethanedionedihydrazone</p>
 
Added Entry - Uncontrolled Name K Patra, Goutam ; Department of Chemistry, Guru Ghasidas Vishwavidyalaya, Bilaspur 495 009, India
Manna, Amit K ; Department of Chemistry, Guru Ghasidas Vishwavidyalaya, Bilaspur 495 009, India
De, Dinesh ; Department of Basic Science, Vishwavidyalaya Engineering College, Lakhanpur, CSVTU, Bhilai 497 116, India
 
Uncontrolled Index Term Hydrazone, quinoline 3-carboxaldehyde, single-crystal X-ray, p-p stacking interactions, supramolecules
 
Summary, etc. <p style="text-align: justify;">The title compound, <em>N</em>,<em>N</em><em>¢</em>-bis (3-quinolylmethylene) diphenylethanedionedihydrazone (<strong>I</strong>) (molecular formula, C<sub>34</sub>H<sub>24</sub>N<sub>6</sub>) has been synthesized by the reaction of quinoline 3-carboxaldehyde and diphenylethanedionedihydrazone in 2:1 molar ratio. The molecular structure has been characterized by room-temperature single-crystal X-ray diffraction which reveals that two quinoline moieties are disposed nearly perpendicularly around the central C-C bond giving an ‘L’ shape to the molecule. This particular geometry gives rise to the hydrogen bonded supramolecular rectangle of two self-complementary molecules. These supramolecular units are further assembled by p-p interaction.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry (IJC)
2022-04-22 16:13:41
 
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http://op.niscair.res.in/index.php/IJC/article/view/62562
 
Data Source Entry Indian Journal of Chemistry (IJC); ##issue.vol## 61, ##issue.no## 4 (2022): Indian Journal of Chemistry-(IJC)
 
Language Note en