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Stereoselective synthetic approach towards phytotoxic agent Agropyrenol

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Title Stereoselective synthetic approach towards phytotoxic agent Agropyrenol
 
Creator Rohith, C S
Anil, T
`Karunakar, B
Narsaiah, A Venkat
 
Subject Agropyrenol
phytotoxic
bromination
detosylation
olefination
 
Description 508-514
A phytotoxic agent Agropyrenol is produced by Ascochyta agropyrina var. nana, in liquid culture. The synthetic
approach has been commenced by using (−)-diethyl-D-tartrate and 2,3-di methyl phenol as building blocks. The key
reactions involved are aromatic sulfone coupling under Julia-Kocienski olefination, selective acetonide protection,
bromination, detosylation and selective oxidation.
 
Date 2022-05-31T06:54:08Z
2022-05-31T06:54:08Z
2022-05
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/59816
 
Language en
 
Publisher NIScPR-CSIR, India
 
Source IJC Vol.61(05) [May 2022]