Synthesis and crystal structure of a distorted face sharing double cubane like tetranuclear NiII-Cu2 II-NiII compound derived from a reduced di-Schiff base ligand
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Title |
Synthesis and crystal structure of a distorted face sharing double cubane like tetranuclear NiII-Cu2 II-NiII compound derived from a reduced di-Schiff base ligand
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Creator |
Hazari, Alokesh
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Subject |
Nickel(II)
Copper(II) Tetranuclear Reduced Schiff base End-on azide |
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Description |
465-471
One new tetranuclear face sharing distorted double cubane like hetero-metallic NiII 2Cu2 II compound has been synthesized using a [NiLR] “metalloligand”, where H2LR = N,N'-bis(2-hydroxybenzyl)-1,3-propanediamine. The compound has been characterized by elemental analysis, spectroscopic methods and single crystal XRD. In the compound, in addition to the 2 -phenoxido bridges, the two terminal NiII atoms are linked to each of the central CuII ion by means of an end-on bridging azido (1,1-N3) ion separately, resulting a tetranuclear cubane like structure. |
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Date |
2022-05-31T07:05:14Z
2022-05-31T07:05:14Z 2022-05 |
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Type |
Article
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Identifier |
2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/59821 |
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Language |
en
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Publisher |
NIScPR-CSIR, India
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Source |
IJC Vol.61(05) [May 2022]
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