Record Details

Synthesis and crystal structure of a distorted face sharing double cubane like tetranuclear NiII-Cu2 II-NiII compound derived from a reduced di-Schiff base ligand

NOPR - NISCAIR Online Periodicals Repository

View Archive Info
 
 
Field Value
 
Title Synthesis and crystal structure of a distorted face sharing double cubane like tetranuclear NiII-Cu2 II-NiII compound derived from a reduced di-Schiff base ligand
 
Creator Hazari, Alokesh
 
Subject Nickel(II)
Copper(II)
Tetranuclear
Reduced Schiff base
End-on azide
 
Description 465-471
One new tetranuclear face sharing distorted double cubane like hetero-metallic NiII
2Cu2
II compound has been synthesized
using a [NiLR] “metalloligand”, where H2LR = N,N'-bis(2-hydroxybenzyl)-1,3-propanediamine. The compound has been
characterized by elemental analysis, spectroscopic methods and single crystal XRD. In the compound, in addition to the
2
-phenoxido bridges, the two terminal NiII atoms are linked to each of the central CuII ion by means of an end-on bridging
azido (1,1-N3) ion separately, resulting a tetranuclear cubane like structure.
 
Date 2022-05-31T07:05:14Z
2022-05-31T07:05:14Z
2022-05
 
Type Article
 
Identifier 2583-1321 (Online); 0019-5103 (Print)
http://nopr.niscpr.res.in/handle/123456789/59821
 
Language en
 
Publisher NIScPR-CSIR, India
 
Source IJC Vol.61(05) [May 2022]