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<p>Synthesis and crystal structure of a distorted face sharing double cubane like tetranuclear Ni<sup>II</sup>-Cu<sub>2</sub><sup>II</sup>-Ni<sup>II </sup>compound derived from a reduced di-Schiff base ligand</p>

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Title Statement <p>Synthesis and crystal structure of a distorted face sharing double cubane like tetranuclear Ni<sup>II</sup>-Cu<sub>2</sub><sup>II</sup>-Ni<sup>II </sup>compound derived from a reduced di-Schiff base ligand</p>
 
Added Entry - Uncontrolled Name Hazari, Alokesh ; Department of Chemistry, Government General Degree College, Singur 712 409, West Bengal, India
 
Uncontrolled Index Term Nickel(II), Copper(II), Tetranuclear, Reduced Schiff base, End-on azide
 
Summary, etc. <p style="text-align: justify;">One new tetranuclear face sharing distorted double cubane like hetero-metallic Ni<sup>II</sup><sub>2</sub>Cu<sub>2</sub><sup>II </sup>compound has been synthesized using a [NiL<sup>R</sup>] “metalloligand”, where H<sub>2</sub>L<sup>R</sup> = N,N'-bis(2-hydroxybenzyl)-1,3-propanediamine. The compound has been characterized by elemental analysis, spectroscopic methods and single crystal XRD. In the compound, in addition to the <em>m</em><sub>2</sub>-phenoxido bridges, the two terminal Ni<sup>II</sup> atoms are linked to each of the central Cu<sup>II</sup> ion by means of an end-on bridging azido (<em>m</em><sub>1,1</sub>-N<sub>3</sub>) ion separately, resulting a tetranuclear cubane like structure.</p>
 
Publication, Distribution, Etc. Indian Journal of Chemistry (IJC)
2022-05-31 17:21:39
 
Electronic Location and Access application/pdf
http://op.niscair.res.in/index.php/IJC/article/view/63634
 
Data Source Entry Indian Journal of Chemistry (IJC); ##issue.vol## 61, ##issue.no## 5 (2022): Indian Journal of Chemistry-(IJC)
 
Language Note en